Chromic triboluminescence of self-assembled platinum(II) complexes.
Chemical communications (Cambridge, England)(2023)
摘要
A series of Pt(II) complexes bearing N-heterocyclic carbenes, [Pt(CN)(Rim-Mepy)] (Rim-MepyH = 3-alkyl-1-(4-methyl-(2-pyridinyl))-1-imidazolium, R = Me, Et, Pr, or Bu), exhibits triboluminescence in the visible range from blue to red, as well as the corresponding intense photoluminescence. Remarkably, among the complexes, the Pr-substituted one exhibits chromic triboluminescence behaviour during the process of rubbing and also vapour exposure.
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