Synthesis of Five-Membered exo-Glycals from Six-Membered 2‑Iodo-endo-glycals

Paul C. Ruer,Youssef Nassar,Peter Polák,Janine Cossy

The Journal of organic chemistry（2023）

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摘要

Five-membered exo-glycals were synthesized from six-membered 2-iodo-endo-glycals by a metal/halogen exchange/ring-opening sequence followed by a cyclization catalyzed by Ag2CO3.

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synthesis,five-membered,six-membered

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