A single-atom cobalt integrated flexible sensor for simultaneous detection of dihydroxybenzene isomers.

Nanoscale(2023)

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摘要
Simultaneous detection of dihydroxybenzene isomers including hydroquinone (HQ), catechol (CC), and resorcinol (RS) is significant for water quality control as they are highly toxic and often coexist. However, it is a great challenge to realize their accurate and simultaneous detection due to their similarity in structure and properties. Herein, an electrochemical flexible strip with single-atom cobalt (SA-Co/NG) was constructed through high-resolution electrohydrodynamic (EHD) printing for dihydroxybenzene isomer's simultaneous detection. Results showed that the provided SA-Co/NG strip exhibited excellent sensing performance with reliable repeatability, reproducibility, long-term stability, and flexibility. Linear ranges of 0.50-31 745 μM, 0.50-5909 μM, and 0.50-153.5 μM were achieved for HQ, CC, and RS, respectively, with a detection limit of 0.164 μM. Based on the experimental data, the mechanism concerning SA-Co/NG catalytic activity towards HQ can be deduced, starting from the combination of Co* and OH in water, followed by the formation of Co-OH-dihydroxybenzene, and finally leading to O-H bond dissociation to generate benzoquinone. As for CC or RS, pyridinic N or CO synergistic with a single Co atom catalyzes their oxidation. Besides, the printed flexible SA-Co/NG strip further demonstrates the accurate and simultaneous detection of HQ, CC, and RS in textile wastewater, proposing a powerful practical application.
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