Corrigendum: Photo-/Electroinduced Irreversible Isomerization of 2,2'-Azobispyridine Ligands in Arene Ruthenium(II) Complexes.

Chemistry (Weinheim an der Bergstrasse, Germany)(2023)

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摘要
In the published article, the 1H and 13C NMR data of trans-2,2’-azobispyridine (E)-1 and cis-2,2’-azobispyridine (Z)-1 were incorrectly reported. The corrected data appearing in the Experimental Section on p. 9568 are given below: trans-2,2’-Azobispyridine (E)-1: 1H NMR (400 MHz, CDCl3): δ ppm 8.79 (m, 2H), 8.01 (dt, J=7.5, 1.0 Hz, 2H), 7.95 (td, J=7.5, 2.0 Hz, 2H), 7.47 (ddd, J=7.5, 5.0, 1.0 Hz, 2H); 13C NMR (100 MHz, CDCl3): δ ppm 162.9, 149.8, 138.7, 126.3, 115.6. cis-2,2’-Azobispyridine (Z)-1: 1H NMR (400 MHz, CDCl3): δ ppm 8.12 (br d, J=5.0 Hz, 2H), 7.75 (td, J=8.0, 1.5 Hz, 2H), 7.36 (br d, J=8.0 Hz, 2H), 7.04 (br dd, J=8.0, 5.0 Hz, 2H); 13C NMR (100 MHz, CDCl3): δ ppm 164.5, 147.8, 137.8, 122.4, 118.6. Please note that the Supporting Information of the original paper has now been replaced by a corrected version. The authors apologize for any inconvenience.
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关键词
ligands,complexes,irreversible isomerization
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