The high-pressure phase diagram of BaNi_2As_2: unconventional charge-density-waves and structural phase transitions

Structural phase transitions accompanied by incommensurate and commensurate charge density wave (CDW) modulations of unconventional nature have been reported in BaNi_2As_2, a nonmagnetic cousin of the parent compound of Fe-based superconductors, BaFe_2As_2. The strong dependence of the structural and CDW transitions of BaNi_2As_2 on isoelectronic substitutions alongside original dynamical lattice effects suggests strong tunability of the electronic phase of the system through structural effects. Here, we present a comprehensive synchrotron x-ray diffraction and first-principles calculation study of the evolution of the crystal structure and lattice instabilities of BaNi_2As_2 as a function of temperature and hydrostatic pressure (up to 12 GPa). We report a cascade of pressure-induced structural phase transitions and electronic instabilities up to 10 GPa, above which all CDW superstructures disappear. We reveal that the stable high-pressure phase consists of planar Ni zigzag chains, from which the surrounding As atoms have been pushed away. This yields a strong reduction of the interlayer As-As distance (along the original c axis), akin to what is observed in the collapsed tetragonal structure of other pnictides, albeit here with a monoclinic structure. The discovery of polymorphs in the pressure-temperature phase diagram of BaNi_2As_2 emphasizes the importance of the relative Ni-Ni and Ni-As bond lengths in controlling the electronic ground state of this compound and increases our understanding of viable electronic phases under extreme conditions.