The 2ν3/ν2/ν5/ν3 + ν6 band system of CH3Br revisited: Anharmonic and Coriolis interactions in a four-level system near 1400 cm−1

Adina Ceausu–Velcescu, Wilfried Tchana Betnga,Fridolin Kwabia Tchana,Laurent Manceron,Xavier Landsheere

Journal of Molecular Spectroscopy（2023）

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摘要

•First accurate modeling of the 2ν3/ν2/ν5/ν3 + ν6 band system of CH3Br, near 1400 cm−1.•Fermi and Coriolis interactions completely understood.•A quantitative reproduction of the available experimental data has been achieved.

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关键词

Methyl bromide,Anharmonic,Coriolis and α-resonance interactions,Combination bands,High resolution,IR absorption

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