C(sp2)–H···π(C≡N) interaction in [Ag+·Argentivorous molecule ⊃ acetonitrile] inclusion complexes

Hiroki Horita,Eunji Lee,Huiyeong Ju,Mari Ikeda,Shunsuke Kuwahara,Yoichi Habata

Inorganica Chimica Acta（2023）

引用 0|浏览7

暂无评分

摘要

•The Ag+ complex with 1a interacts with CH3CN molecules at both the (CN) of CH3CN and the CH(sp2) of the aromatic side-arms in the solid state.•The DFT calculations revealed electron donation from the CH(sp2) of the styrylmethyl group to the C(sp) and N(sp) atoms of acetonitrile.•The CH(sp2)··· π(C≡N) interaction observed in this study represents the first experimental example.

查看译文

关键词

C(sp2)-H··· π(C≡N) Interaction,Argentivorous molecules,silver(I) complexes,DFT calculations,Macrocycles,X-ray structure

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要