Covalent modification of glassy carbon surface via radical-induced grafting from electrochemical oxidation of imine derivatives

Carolina P. Candia,Elizabeth Imbarack,Carlos P. Silva,Camila F. Olguín, Geraldine Jara, Sandra Fuentes,José H. Zagal,Nicolás Agurto,Jorge Pavez

Electrochimica Acta（2023）

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摘要

•A novel and effective method for controlled modification of glassy carbon surfaces.•Glassy carbon surface was modified by imine derivative radical-induced electrochemical grafting.•Imine bonds are cleaved during electrochemical oxidation.•Covalent modification of GC surfaces by forming C(surface)-N bonds.

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关键词

Surface grafting, Ferrocenyl imine spectroelectrochemistry, Radical-induced grafting, In-situ, operando conditions

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