Full-spectrum broad-spectrum degradation of antibiotics by BiVO4@BiOCl crystal plane S-type and Z-type heterojunctions

•BiVO4@BiOCl crystal plane S-type and Z-type heterojunctions were prepared.•Selective induction of OVs formation by heterogeneous and homogeneous nucleation.•Heterojunctions have good broad-spectrum degradability in the full spectrum.•The degradation of TC by heterojunctions was 90.32% (Vis)/71.17% (NIR).•Good degradation performance of heterojunctions for mixed antibiotics under Vis/NIR.