Toluene and 2-propanol mixture oxidation over Mn2O3 catalysts: Study of inhibition/promotion effects by in-situ DRIFTS

E.J. Moreno-Román,J. González-Cobos, N. Guilhaume,S. Gil

Chemical Engineering Journal（2023）

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摘要

•Mn2O3 oxides are active for the oxidation of toluene, 2-propanol and their mixture.•Mn2O3 catalyst prepared by Citrate-Gel method has the best catalytic performances.•The presence of both VOCs promoted the deep oxidation of each other on Mn2O3.•The promotion effect of binary mixture above 200 °C was proven by in-situ DRIFTS.•DRIFTS allowed to identify the reaction intermediates in different scenarios.

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关键词

Manganese oxides-based catalysts, VOCs binary mixture catalytic oxidation, In-situ surface measurements, Reaction mechanisms

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