Band-gap reduction of oxides via partial hydrolysis-enhanced carbothermic reaction

Applied Materials Today(2023)

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摘要
•Limited hydrolysis-facilitated carbothermic reaction produces black titania and black zirconia.•Defects thus induced belong to the deep-level defects, leading to improved photothermal performance.•The black color can be ascribed to the d-d transition.
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关键词
Hydrolysis, Carbothermic reactions, Band gap, Oxygen vacancy, d -d transition
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