Quantum phase transitions probed by EPR spectra in dimeric spin arrays with supramolecular couplings

Rafael Calvo,Rosana P. Sartoris,Otaciro R. Nascimento,Matúš Šedivý,Antonin Sojka,Petr Neugebauer,Vinicius T. Santana

Coordination Chemistry Reviews（2023）

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摘要

•Quantum phases observed with EPR in coupled dimeric spin arrays are explained.•Interdimeric exchange results in flip-flop of triplet excitations observed by EPR.•Weak interdimeric exchange introduce features in crystal and powder EPR spectra.

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关键词

epr spectra,dimeric spin arrays,phase transitions,supramolecular

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