Molecular catalysts for CO2 Electroreduction: Progress and prospects with pincer type complexes

Hussein A. Younus,Nazir Ahmad,Wenpeng Ni,Xiwen Wang,Mohammed Al-Abri,Yan Zhang,Francis Verpoort,Shiguo Zhang

Coordination Chemistry Reviews（2023）

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摘要

•Fundamentals and metrics for evaluation of CO2 reduction reaction (CO2RR) electrocatalysts.•Pioneering and recent examples of pincer-based molecular catalysts in CO2RR.•Effect of ligand structure, metal type, and reaction conditions on product selectivity and catalysts’ stabilities in CO2RR.•Heterogenization of pincer-based molecular catalysts for CO2RR, and its impact on reduction products.•Mechanistic understanding of CO2RR using pincer-based molecular catalysts.

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关键词

Electrocatalysis, Electroreduction, CO2 reduction reaction, CO2RR, Molecular catalyst, Pincer complex

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