Tetraphenylethene-linked octacationic dicyclophanes with enhanced recognition of NADH over NAD+ in water

Ling Wang, Zhihui Guo,Lin Cheng,Hao Nian,Nuojin Yao,Yanxia Zhao,Kai Liu,Liping Cao

Dyes and Pigments（2023）

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摘要

Tetraphenylethene-linked octacationic dicyclophanes (1, 2 and 3) with dual cavities were designed and synthesized via one-step SN2 reaction. These water-soluble dicyclophanes could bind nicotinamide adenine dinucleotides to form 1:2 host-guest complexes in water, and exhibit an enhanced recognition toward NADH over NAD+ through the cooperative endo- and exo-host-guest interactions.

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关键词

Tetraphenylethene, Octacationic dicyclophanes, Host -guest recognition, Nicotinamide adenine dinucleotides, Supramolecular chemistry

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