Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application

JOURNAL OF MOLECULAR LIQUIDS(2023)

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摘要
The primary objective of the present work is to carry out an experimental study into the stability and thermophysical characteristics of cellulose nanocrystal, MXene, and hybrid cellulose nanocrystal-MXene added to engine oil as a lubricant for piston ring-cylinder liner application. There have been experiments with stability techniques like sedimentation observation, UV-visible spectroscopy, and zeta potential. Thermophysical characteristics have been measured using the viscosity index, dynamic viscosity, and thermal conductivity at various concentrations (ranging from 0.01 % to 0.05 %) and temperatures (from 40 degrees C to 100 degrees C). Even without any surfactants, the cellulose nanocrystal-MXene nanolubricants showed good dispersion during the first seven days. The results of the ultraviolet-visible spectrophotometer indicate that cellulose nanocrystal nanolubricants exhibit an absorbance ratio that is most similar to one. It can be shown that the zeta potential increases with a concentration in the distribution of cellulose nanocrystal, MXene, and cellulose nanocrystal-MXene nanoparticles. According to the viscosity index results, all nanolubricants reduce the lubricity oil's viscosity by 16.77 % to 20.33 %, with cellulose nanocrystal-MXene showing the greatest improvement at 0.05 %. At solid concentrations of 0.01 % cellulose nanocrystal and 0.05 % cellulose nanocrystal-MXene with temperatures of 40 degrees C and 90 degrees C, the dynamic viscosity was enhanced by 0.92 % and 130.87 %, respectively. The solid concentration of 0.05 % cellulose nanocrystal-MXene was determined to have the greatest effect on the thermal conductivity ratio of the chosen nanolubricant at 90 degrees C. Overall, at an average concentration of 0.05 %, the thermophysical properties' performance was increased by the addition of cellulose nanocrystal-MXene nanoparticle. The study's findings may be useful for applications involving heat transmission, particularly tribological ones.
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关键词
thermophysical properties,cnc-mxene
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