Wide band tri-receptor quaternary organic photodetector based on PC61BM, ITIC, and IICO-4F

In this paper, we report a wide band spectrum tri-receptor quaternary organic photodetector (OPD) based on the additional two non-fullerene acceptor materials, ITIC and IEICO-4F, with the polymer material P3HT as donor and the fullerene PC61BM as the first acceptor. The second acceptor ITIC and the third accptor IEICO-4F, with different molecular structures and absorption, were introduced into the conventional system P3HT:PC61BM to improve narrow response spectral range and the uneven response of OPDs. The experiments results show, that proposed non-fullerene acceptor materials of the narrow optical band gap were successful to broaden the absorption spectral range to near infrared. Respectively, the responses (R) and external quantum efficiency at 630, 530, and 460 nm, are up to 0.293 A W-1, 0.288 A W-1, 0. 243 A W-1, and 58%, 67%, and 66%. The quaternary OPDs achieve significant response spectrum across the 400-950 nm range with the specific detection rate (D*) exceeding 10(12) Jones. It demonstrates that expanding spectrum non-fullerene materials ITIC and IEICO-4F can improve the mixing degree of the mixed materials, decrease agglomeration brought on by single widening excess, and increase spectrum absorption and moderate non-uniform response. The exciton dissociation efficiency is considerably increased by simultaneous charge transfer between the receptors and the receptors in the active layer. Moreover, the carrier mobility is improved, bimolecular recombination is suppressed.