Correlation of Neogene Oil and Paleogene Source Rocks in the Middle Huanghekou Sag, Bohai Bay Basin

Several billion-ton Neogene oil fields have been successfully discovered in the middle Huanghekou sag over the past few years. However, the source of the crude oil needs to be clarified, and the relevant oil-source correlation was less carried out. Six source rocks of the third member of the Paleocene Shahejie Formation (Es3) from five wells and sixteen Neogene crude oil samples from nine wells in the middle Huanghekou sag were investigated for the oil-source correlation with the biomarkers and carbon and hydrogen isotopes of saturated hydrocarbon monomers. The distribution characteristics of n-alkanes, C19/C23 ratio of tricyclic terpanes, long-chain tricyclic terpene ratios (ETR), C24 tetracyclic terpane to C26 tricyclic terpene, and distribution characteristics of conventional steranes suggest that the Es3 parent material is of a mixed-source input from terrestrial higher plants and aquatic phytoplankton. The gammacerane to C-30 hopane ratio is low, ranging from 0.094 to 0.134, with a mean value of 0.118; the Pr/Ph ratio is less than 1.5. The Neogene oils show the characteristics of a saturated hydrocarbon biomarker similar to Es3. The carbon and hydrogen isotopes of saturated hydrocarbon monomers also corroborate the oil-source correlation from the depositional environment and parent material source, which characterize the low salinity of the water during the Es3 sedimentary period, which was a brackish or a freshwater delta deposition under weak oxidation-weak reduction conditions. The parity dominance of CPI and OEP values (both greater than 1), higher ratios of Ts/Tm (1.174 to 1.383, mean 1.278) and the C29Ts/C-29 norhopane, high values of diahopane and diasterane contents (C(30)diaH/C30H, C(27)diaS/C27S), and hopane and sterane isomerization parameters (%22S, %20S, % beta beta) confirm that the E-s3 source rock samples are mature enough to provide crude oil for the middle Huanghekou sag. The biomarker characteristics of regional Neogene crude oil are significantly different from those of Es-4 source rocks in the surrounding depressions (sags), indicating the Es-4 strata's absence in the middle Huanghekou sag. Suitable traps need to be discovered around the hydrocarbon-generating center of the Es-3 source rock for oil and gas exploration in the future.