Compact accumulation of superatomic silver nanoclusters with an octahedral Ag₆ core ligated by trithiane

Two superatomic solids, a bi-cluster compound, [Ag6(3S)4(OTf)4][Ag6(3S)4(CCtBu)4](OTf)2 [Ag6(0)·Ag6(i)], and a homologous nanocluster, [Ag6(3S)4(tfa)4] (Ag6), have been described here, which are both close-packed in the crystal lattice with the ligation of trithiane.