Visible-light NO photolysis of ruthenium nitrosyl complexes with N₂O₂ ligands bearing π-extended rings and their photorelease dynamics

Minyoung Kim,Seongchul Park,Dayoon Song, Dohyun Moon,Youngmin You,Manho Lim,Hong-In Lee

Dalton Transactions（2022）

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摘要

{Ru–NO}6 complexes with N2O2 ligands bearing π-extended rings effectively release NO under visible light excitation. Their Ru–NNO bond-dissociation is initiated by a ligand-to-ligand charge transfer.

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Visible-light NO photolysis of ruthenium nitrosyl complexes with N2O2 ligands bearing π-extended rings and their photorelease dynamics

Visible-light NO photolysis of ruthenium nitrosyl complexes with N₂O₂ ligands bearing π-extended rings and their photorelease dynamics