Organocatalytic formal [3 + 3] cyclization of α-(6-indolyl) propargylic alcohols

Zhibin Yue,Ziyang Wang, Yunfeng Zhang,Xuling Chen,Pengfei Li,Wenjun Li

Organic & Biomolecular Chemistry（2022）

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摘要

A acetic acid mediated 1,10-conjugate addition-mediated formal [3 + 3] cyclization of alkynyl indole imine methides formed in situ from α-(6-indolyl) propargylic alcohols with 1,3-dicarbonyl compounds such as 4-hydroxycoumarins and cyclohexane-1,3-diones was developed.

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