Crossover From Cooper-Pair Hopping to Single-Electron Hopping in Pb_x(TiO_2)_1-x Granular Films

The electrical transport properties of Pb_x(TiO_2)_1-x (x being the Pb volume fraction and ranging from ∼0.45 to ∼0.69) granular films are investigated experimentally. The charging energy of the Pb granules is reduced to less than the superconducting gap of Pb granules for the low temperature insulating films by using high-k dielectric TiO_2 as the insulating matrix. For the insulating films in the vicinity of the superconductor-insulator transition, Cooper-pair hopping governs the low-temperature hopping transport. For these films, the low-temperature magnetoresistance is positive at low field and the resistivity vs temperature for Cooper-pair hopping obeys an Efros-Shklovsii-type variable-range-hopping law. A crossover from Cooper-pair-dominated hopping to single-electron-dominated hopping is observed with decreasing x. The emergence of single-electron-dominated hopping in the more insulating films is due to the causation that the intergrain Josephson coupling becomes too weak for Cooper pairs to hop between adjacent superconducting Pb granules.