Photoresponsive gadolinium–anthracene complexes: tuning the orientation and π–π stacking of anthracene groups via alkyl ester substituents of phosphonate ligands

Xin-Da Huang,Guo-Bin Sun,Yi-Qing Chen,Ge-Hua Wen,Song-Song Bao,Li-Min Zheng

CrystEngComm（2022）

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摘要

[Gd(NO3)3(LR)2(dmpu)] containing 9-dialkyl phosphonomethylanthracene [LR, R = Me (1), Et (2), i-Pr (3)] show [4 + 4] photocycloaddition reaction for 1 and 2, but not for 3.

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关键词

phosphonate ligands,gadolinium–anthracene groups,photoresponsive gadolinium–anthracene,complexes

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