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Synthesis, structure and reactivity of μ3-SnH capped trinuclear nickel cluster

Nicole A. Torquato,Joseph M. Palasz,Quentin C. Bertrand,Felix M. Brunner,Thomas Chan, Milan Gembicky,Anthony A. Mrse,Clifford P. Kubiak

Chemical Science（2022）

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摘要
The synthesis, structure, and reactivity of a μ3-SnH capped trinuclear nickel cluster, [Ni3(dppm)3(μ3-H)(μ3-SnH)], is reported. This complex undergoes oxidative addition chemistry, alkyne insertion, and subsequent hydrogenation.
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