Synthesis of cyano-substituted γ-lactams through a copper-catalyzed cascade cyclization/cyanation reaction

Wen Liu,Liang Wang, Haiping Mu,Qian Zhang,Zeguo Fang, Dong Li

Organic & Biomolecular Chemistry（2023）

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摘要

A copper-catalyzed cascade cyclization/cyanation of N-aryl-4-pentenamides with TMSCN was developed. The reaction proceeded in water under simple conditions to generate a series of cyano-substituted γ-lactam derivatives.

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关键词

cascade cyclization/cyanation,synthesis,cyano-substituted,copper-catalyzed

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