High-nuclearity and thiol protected core–shell [Cu₇₅(S-Adm)₃₂]²⁺: distorted octahedra fixed to Cu₁₅ core via strong cuprophilic interactions

Jie Tang,Chong Liu,Chenyu Zhu,Keju Sun,He Wang,Wen Yin,Chuting Xu,Yang Li,Weiguo Wang,Li Wang,Renan Wu,Chao Liu,Jiahui Huang

Nanoscale（2023）

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摘要

[Cu75(S-Adm)32]2+ was constructed by 12 distorted octahedra and face centered cubic Cu15 core, and contains the shortest Cu–Cu bond length (2.166(7) Å), indicating the strong cuprophilic interactions in the Cu75 nanocluster.

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thiol,core–shell,cu75s-adm322+,high-nuclearity

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High-nuclearity and thiol protected core–shell [Cu75(S-Adm)32]2+: distorted octahedra fixed to Cu15 core via strong cuprophilic interactions

High-nuclearity and thiol protected core–shell [Cu₇₅(S-Adm)₃₂]²⁺: distorted octahedra fixed to Cu₁₅ core via strong cuprophilic interactions