Synthesis of α-pyrones via gold-catalyzed cycloisomerization/[2 + 1] cycloaddition/rearrangement of enyne-amides and sulfur ylides

Jinhang Yu,Xinyuan Wang,Mengjiao Xu, Bei Zhang,Zuping Xiong,Hui Mao,Xin Lv,Liejin Zhou

Organic Chemistry Frontiers（2023）

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摘要

A novel gold-catalyzed cycloisomerization/[2 + 1]cycloaddition/rearrangement of enyne-amides and sulfur ylides is reported. This strategy enables rapid and efficient construction of a series of α-pyrone derivatives.

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关键词

synthesis,cycloaddition/rearrangement,gold-catalyzed,enyne-amides

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