Strain engineering of Li⁺ ion migration in olivine phosphate cathode materials LiMPO₄ (M = Mn, Fe, Co) and (LiFePO₄)_n(LiMnPO₄)_m superlattices

Wang Zhang, Fu-Ye Du,Yang Dai,Jin-Cheng Zheng

Physical Chemistry Chemical Physics（2023）

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摘要

In olivine phosphate cathode materials, the biaxial tensile strain perpendicular to the direction of Li+ ion migration is the most favorable for Li+ ion migration, and the b-axial strain has a greatest effect on the Li+ ion migration barrier.

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关键词

ion migration,strain,superlattices

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Strain engineering of Li+ ion migration in olivine phosphate cathode materials LiMPO4 (M = Mn, Fe, Co) and (LiFePO4)n(LiMnPO4)m superlattices

Strain engineering of Li⁺ ion migration in olivine phosphate cathode materials LiMPO₄ (M = Mn, Fe, Co) and (LiFePO₄)_n(LiMnPO₄)_m superlattices