Formation of a Polar Flow Channel with Embedded Gas Recognition Pockets in a Yttrium-Based MOF for Enhanced C₂H₂/C₂H₄ and CO₂ Selective Adsorptions

Mingxing Zhang,Penghui Liu,Rui Dang,Huihui Cui,Guomin Jiang,Jin Wang,Miao Wang,Tongming Sun,Minmin Wang,Guoping Qin,Su Wang,Yanfeng Tang

Inorganic Chemistry（2022）

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摘要

A polar flow channel with embedded gas recognition pockets was made in a 10-connected hexanuclear yttrium-based metal-organic frameworks (MOF) NTUniv-57 (NTUniv = Nantong University) by lowering the symmetry of the ligand, which showed high chemical stability and obviously enhanced gas adsorption selectivities.

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polar flow channel,embedded gas recognition pockets,mof,yttrium-based

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Formation of a Polar Flow Channel with Embedded Gas Recognition Pockets in a Yttrium-Based MOF for Enhanced C2H2/C2H4 and CO2 Selective Adsorptions

Formation of a Polar Flow Channel with Embedded Gas Recognition Pockets in a Yttrium-Based MOF for Enhanced C₂H₂/C₂H₄ and CO₂ Selective Adsorptions