Binuclear coordination complex of open merocyanine form of photochromic spiropyran with Mn^II(hfac)₂ having high spin (S = 5) ground state

Nikita G. Osipov,Maxim A. Faraonov,Alexander F. Shestakov,Maxim V. Mikhailenko,Alexey V. Kuzmin,Salavat S. Khasanov,Akihiro Otsuka,Hideki Yamochi,Hiroshi Kitagawa,Dmitri V. Konarev

New Journal of Chemistry（2023）

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摘要

The interaction of 1,3,3-trimethylindolino-β-naphthopyrylospiran (TMI-NPS) with manganese(ii) hexafluoroacetylacetonate yields crystals of {MnII(hfac)2 (μ2-TMI-NPS)}2 (1) in which Mn(ii) atoms are bridged by oxygen atoms of ring-opened TMS-BPI into the dimer.

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Binuclear coordination complex of open merocyanine form of photochromic spiropyran with MnII(hfac)2 having high spin (S = 5) ground state

Binuclear coordination complex of open merocyanine form of photochromic spiropyran with Mn^II(hfac)₂ having high spin (S = 5) ground state