The reactivity of antimony and bismuth N,C,N-pincer compounds toward K[BEt₃H] – the formation of heterocyclic compounds vs. element–element bonds vs. stable terminal Sb–H bonds

Pavel Novák,Milan Erben,Roman Jambor,Martin Hejda,Aleš Růžička,Elena Rychagova,Sergey Ketkov,Libor Dostál

Dalton Transactions（2023）

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摘要

A diverse reactivity of Sb(iii) and Bi(iii) N,C,N pincer complexes toward K[BEt3H] is reported along with a remarkable epimerization of chiral E–E bonded compounds.

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关键词

antimony,heterocyclic compounds,element–element bonds,bismuth

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The reactivity of antimony and bismuth N,C,N-pincer compounds toward K[BEt3H] – the formation of heterocyclic compounds vs. element–element bonds vs. stable terminal Sb–H bonds

The reactivity of antimony and bismuth N,C,N-pincer compounds toward K[BEt₃H] – the formation of heterocyclic compounds vs. element–element bonds vs. stable terminal Sb–H bonds