Carbon dioxide uptake by [Cu(bpca)]⁺: synthesis, crystal structure, and magnetic properties of {[Na(H₂O)₂][Cu₂(bpca)₂(CO₃)(HCO₃)]}_n [Hbpca = bis(2-pyridylcarbonyl)amide]

Rafaela M. R. da Silva,Iara M. L. Rosa,Willian X. C. Oliveira,Odivaldo C. Alves,Evelyn C. S. Santos,Flávio Garcia,Henrique C. Silva Junior,Glaucio B. Ferreira,Guilherme P. Guedes,Walace D. do Pim,Miguel Julve,Maria Vanda Marinho

New Journal of Chemistry（2023）

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摘要

Carbon dioxide fixation by [Cu(bpca)(H2O)]2+ resulted in a chain having CO32− and HCO3− as ligands that shows a weak intrachain ferromagnetic interaction.

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carbon dioxide,crystal structure

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Carbon dioxide uptake by [Cu(bpca)]+: synthesis, crystal structure, and magnetic properties of {[Na(H2O)2][Cu2(bpca)2(CO3)(HCO3)]}n [Hbpca = bis(2-pyridylcarbonyl)amide]

Carbon dioxide uptake by [Cu(bpca)]⁺: synthesis, crystal structure, and magnetic properties of {[Na(H₂O)₂][Cu₂(bpca)₂(CO₃)(HCO₃)]}_n [Hbpca = bis(2-pyridylcarbonyl)amide]