Photoredox-catalyzed coupling of aryl sulfonium salts with CO₂ and amines to access O-aryl carbamates

Yanhui Guo,Li Wei,Zhonglin Wen,Huanfeng Jiang,Chaorong Qi

Chemical Communications（2023）

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摘要

A two-step sequence to valuable O-aryl carbamates through site-selective C–H thianthrenation of arenes and photoredox-catalyzed carbamoyloxylation with CO2 is reported.

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Photoredox-catalyzed coupling of aryl sulfonium salts with CO2 and amines to access O-aryl carbamates

Photoredox-catalyzed coupling of aryl sulfonium salts with CO₂ and amines to access O-aryl carbamates