Peptide-bridged bis-porphyrin compounds: A photophysical and molecular dynamics study

Journal of Photochemistry and Photobiology(2023)

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摘要
•Homoenergy transfer between a peptide-bridged porphyrin pair is mediated by exciton migration.•The rigidity of peptide spacers promotes self-trapping of exciton species.•Tetrasubstituted amino acids form rigid peptide bridges spacing antenna chromophores.
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关键词
Bis-porphyrins,Exciton coupling,Peptide spacers,Singlet oxygen production,Time-resolved spectroscopy,Ultrafast transient absorption
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