Peripheral nucleic bases boost H-2 production by synthetic molecular catalysts in acidic water

Srewashi Das,Chandan Das, Naseer Ahmad Shah,Santanu Ghorai,Piyali Majumder,Arnab Dutta

CHEMICAL COMMUNICATIONS（2023）

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摘要

The strategic inclusion of nucleic bases adenine, cytosine, and thymine, in the form of outer coordination sphere, positively impacts the electro- and photocatalytic H-2 production by cobaloxime cores. These cobaloxime derivatives showcased their optimal H-2 production in acidic media due to specific protonation of adenine and cytosine below pH 5.0.

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关键词

synthetic molecular catalysts,peripheral nucleic bases,water

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