Review of the Scalable Core-Shell Synthesis Methods: The Improvements of Li-Ion Battery Electrochemistry and Cycling Stability

The demand for lithium-ion batteries has significantly increased due to the increasing adoption of electric vehicles (EVs). However, these batteries have a limited lifespan, which needs to be improved for the long-term use needs of EVs expected to be in service for 20 years or more. In addition, the capacity of lithium-ion batteries is often insufficient for long-range travel, posing challenges for EV drivers. One approach that has gained attention is using core-shell structured cathode and anode materials. That approach can provide several benefits, such as extending the battery lifespan and improving capacity performance. This paper reviews various challenges and solutions by the core-shell strategy adopted for both cathodes and anodes. The highlight is scalable synthesis techniques, including solid phase reactions like the mechanofusion process, ball-milling, and spray-drying process, which are essential for pilot plant production. Due to continuous operation with a high production rate, compatibility with inexpensive precursors, energy and cost savings, and an environmentally friendly approach that can be carried out at atmospheric pressure and ambient temperatures. Future developments in this field may focus on optimizing core-shell materials and synthesis techniques for improved Li-ion battery performance and stability.