Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes

Jun Zhou,Zhengyu Zhao,Bingyao Jiang,Katsuhiro Yamamoto,Yuji Sumii,Norio Shibata

Chemical Science（2023）

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摘要

Silylboronate-mediated radical cross-coupling of aryl fluorides with arylalkanes is disclosed for the efficient defluoroalkylation enabling a mild construction of a new C–C bond by selectively coupling a C(sp2)–F and C(sp3)–H bond.

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