A dense 3d–4f metal–organic framework with “gas pockets” for highly efficient CH₄/N₂ separation

Li-Min Zhu,Wen-Liang Li,Tian-Ran Li,Lin-Ping Shi,Li-Ting Li,Zhao-Quan Yao,Hong-Liang Huang,Jiong-Peng Zhao,Fu-Chen Liu

Inorganic Chemistry Frontiers（2023）

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摘要

A pillar-layered dense 3d–4f MOF shows high IAST selectivity for CH4/N2 owing to the enhancement of the interactions between the MOF and CH4 by the heteroatoms of the pillars.

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A dense 3d–4f metal–organic framework with “gas pockets” for highly efficient CH4/N2 separation

A dense 3d–4f metal–organic framework with “gas pockets” for highly efficient CH₄/N₂ separation