Cu(i)-catalysed cross-coupling reaction of in situ generated azomethine ylides towards easy construction of fused N-heterocycles

Sabir A. Molla,Debasish Ghosh, Ankur Basak,Saikat Khamarui,Dilip K. Maiti

Chemical Communications（2023）

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摘要

We disclosed a decarboxylative generation of stabilized azomethine ylides using K2CO3 and CuI-catalyzed regiospecific C–C/C–S and C–C/C–N coupled cyclization to furnish 5,6,7,8a-tetrahydropyrrolo[2,1-b]thiazoles and 6,7-dihydro-5H-pyrrolo[1,2-a]imidazoles, respectively.

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