Nitrogen-containing carbon nanofibers as supports for bimetallic Pt-Mn catalysts in aqueous phase reforming of ethylene glycol

Aqueous phase reforming (APR) of ethylene glycol was performed at 225 degrees C and 30 bar in batch and continuous reaction conditions. The effect on the APR performance by functionalizing carbon supports with nitrogen and adding Mn to Pt-based catalysts was investigated. The presence of nitrogen species on the carbon surface and Mnaddition (PtMn) improved the catalytic activity and promoted H2 production. XPS results suggest that the enhancement of the catalytic activity may be attributed to charge transfer from platinum to the nitrogen groups and Mn. Pt-based catalysts were stable under the studied reaction conditions, while up to 97 % of the manganese leached into the liquid solution during APR. However, the catalytic activity was maintained even with such significant decrease in Mn content, indicating that only a small amount of Mn is necessary to maintain the promotional effect on Pt during APR.