Expanded graphite/Co@C composites with dual functions of corrosion resistance and microwave absorption

The development of microwave absorption materials with good environmental adaptability is a hot topic in the electromagnetic protection field. In this research, Expanded graphite (EG)/ ZIF-67 nanocubes-derived (Co@C) composites were successfully fabricated by electrostatic assembly and subsequent heat treatment. The results show that the involvement of an appropriate content of Co@C not only overcomes the problem of single EG impedance mismatch but also introduces additional magnetic loss for the absorber. At the thicknesses of 1.6 mm and 1.5 mm, an effective absorption bandwidth (EAB) of 4.52 GHz and a minimum reflection loss (RLmin) of -48.4 dB were achieved for the Z2-700 sample with a low filling ratio (20 wt%). The enhancement of EMW-absorption performance is attributed to the optimiza-tion of impedance matching and the synergistic action between multiple loss mechanisms. Electrochemical corrosion test showed that graphite nanoflakes of EG enhanced the transfer resistance during corrosion, and the corrosion resistance of pure Co@C was enhanced with the protection of EG. This work provides a reasonable attempt to design and fabricate effi-cient microwave absorption materials suitable for harsh environments.(c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).