Effect of Clay Minerals and Rock Fabric on Hydrocarbon Generation and Retention by Thermal Pyrolysis of Maoming Oil Shale

In traditional kerogen pyrolysis experiments, the effects of minerals and rock fabric on the pyrolysis products were ignored. To further clarify the role of the mineral matrix and rock fabric on hydrocarbon generation and retention, a closed anhydrous pyrolysis experiment was conducted on core plugs, powdered rock and kerogen from a clay-rich sample of Maoming oil shale within a temperature range of 312 degrees C to 600 degrees C, at a fixed pressure of 30 Mpa. The experiment's results showed that the yields of heavy hydrocarbons (C14+) generated from the core plugs and powdered rock were obviously lower than that of kerogen, which may be caused by the retention effect of clay minerals in raw shale. The yields of gaseous hydrocarbons generated from core plugs were lower compared with powdered rock due to the retention of C2+ hydrocarbons by the intact rock fabric and the preferential generation of methane. Light hydrocarbon (C6-14) yields generated from the core plugs and powdered rock were higher than kerogen, which may be the consequence of the cleavage of extraction bitumen and the interactions with kerogen. Moreover, the ratios of iso to normal paraffin (iC(4)/nC(4), iC(5)/nC(5)) of the core plugs and powdered rock were higher than kerogen. Our experimental results show that kerogen pyrolysis in a confined system may overestimate the hydrocarbon generation potential due to the negligence of the retention effect of minerals and the rock fabric, especially in the source rocks rich in clay minerals.