Synthesis of -iodovinyl sulfones via direct photoinitiated difunctionalization of internal alkynes
Organic & biomolecular chemistry(2023)
摘要
The reaction of direct photoinitiated iodosulfonylation of internal acetylenes with p-tolylsulfonyl iodide and its regioselectivity of the products was studied. Methods for the subsequent functionalization of beta-iodovinylsulfones using cross-coupling reactions to obtain valuable and non-available compounds are proposed.
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关键词
direct photoinitiated difunctionalization,internal alkynes,synthesis
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