Combining local conformational preferences and solvophobic effects in helical aromatic oligoamide foldamers.

Organic & biomolecular chemistry(2023)

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摘要
Aromatic oligoamide foldamers were designed using a newly-developed monomer so that helical folding was promoted by both local conformation preferences and solvophobic effects. Solid phase synthesis provided quick access to the desired sequences. Sharp solvent-driven conformational transitions that depended on sequence length were evidenced by both NMR and UV absorption spectroscopies.
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local conformational preferences
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