Co2+, Ni2+ and Cu2+ complexes with phosphorylated derivatives of cyclen and diaza-18-crown-6: Effect of anion on the structure of complexes and their stability in solution

Galina S. Tsebrikova,Irina S. Ivanova,Andrey B. Ilyukhin,Ilya A. Yakushev,Pavel V. Dorovatovskii,Vitaly P. Solov'ev,Vladimir E. Baulin,Aslan Yu. Tsivadze

Inorganica Chimica Acta（2023）

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摘要

•Phosphorylated cyclen and diaza-18-crown-6 derivatives were synthesized.•Its complexes with MA2 (M = Co2+, Ni2+, Cu2+, A = ClO4-, NCS-, NO3–) were studied.•Structure of complex cation [CoL1]2+ is dependent on the type of anion.•Stability constants of Co2+ complexes with L1 increase in the NCS-更多

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关键词

Phosphorylated cyclen,Diaza-18-crown-6,Cobalt(II),Nickel(II),Copper(II),Stability constant

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