Visible-Light-Induced Oxidative Carboazidation of Arylacrylamides

Congcong Pei,Yanpeng Liu,Xiaoyu Chen,Jingya Li,Dapeng Zou,Yangjie Wu,Yusheng Wu

ADVANCED SYNTHESIS & CATALYSIS（2023）

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摘要

A visible-light-induced oxidative carboazidation of arylacrylamides by cascade C-N and C-C bond-forming strategy is reported. Various functional groups are tolerated to afford the desired azide oxindoles in 22-86% yields under the standard conditions. Mechanistic studies demonstrate that the reaction proceeded via a radical pathway.

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关键词

Carboazidation,Cyclization,Radicals,Visible-light,TMSN3

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