Hierarchical wormlike engineering: Self-assembled SnS2 nanoflake arrays decorated on hexagonal FeS2@C nano-spindles enables stable and fast sodium storage
CHEMICAL ENGINEERING JOURNAL(2023)
摘要
The exploitation of advanced electrode materials with an unique hierarchical architecture and physicochemical feature undertakes an extremely prominent role in achieving rapid ion-transport and remarkable performance to further promote the development of highly efficient sodium-ion batteries (SIBs). Herein, a multi-step synthesis tactic involving in-situ polymerization of dopamine, high-temperature sulfuration and subsequent solvothermal was put forward for the construction of exquisitely hierarchical wormlike architecture by growing SnS2 nano -flake arrays on hexagonal FeS2@C nano-spindles (FeS2@C@SnS2) utilizing tailor-made Fe-based metal-organic framework nanorod as an initial template. The experimental results combined with theoretical analysis thor-oughly disclose that the successful construction of the hierarchical wormlike FeS2@C@SnS2 architecture can markedly afford sufficient active reaction sites and favorable Na+ adsorption, as well as accelerate ion-diffusion kinetics and enhance surface-capacitive contribution, thereby synergistically making its higher initial coulombic efficiency, more outstanding cycling capability and rate performance than FeS2@C and SnS2 samples. Specif-ically, the FeS2@C@SnS2 composite delivers an attractive reversible capacity up to 585.7 mAh g-1 over 1000 cycles at 1.0 A g-1, outstanding high-rate, and durable sodium storage features (only 0.07 % capacity fading each cycle over 2800 cycles at 20.0 A g-1). Moreover, ex-situ experimental characterizations systematically unravel the FeS2@C@SnS2 experiences phase transformations of preliminarily proceeding with the Na+ insertion, fol-lowed by the conversion and further alloying-dealloying reaction mechanism. Prompted by the above advan-tages, the FeS2@C@SnS2||Na3V2(PO4)3@C full cell presents its potential application feasibility toward SIBs, achieving good cycling performance and seductive specific capacity.
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关键词
Hierarchical engineering,Metal sulfides,FeS 2 @C@SnS 2 composite,Sodium ion batteries,Anode
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