Electroluminescent property of new chrysene derivatives having bulky side group of aromatic amine moiety

MOLECULAR CRYSTALS AND LIQUID CRYSTALS(2023)

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摘要
Two blue emitting materials, 4,4'-(chrysene-6,12-diyl)bis(N,N-diphenylaniline) (TPA-C-TPA) and 12-(4-(diphenylamino)phenyl)-N,N- Diphenylchrysen-6-amine (TPA-C-DPA) were prepared with the composition of chrysene core moiety and dipenylamine (DPA) and triphenylamine (TPA) moieties as the side group. Two compounds were used to emitting layer as the dopants (EMLs) in doped device. The doped device using TPA-C-TPA showed current efficiency of 2.49 cd/A and external quantum efficiency of 4.26% at a current density of 10 mA/cm(2). The doped device using TPA-C-DPA exhibited CE of 2.28 cd/A and EQE of 3.52% at a current density of 10 mA/cm(2). TPA-C-TPA and TPA-C-DPA show the Commission Internationale de L'Eclairage (CIE) coordinates of (0.15, 0.06) and (0.14, 0.06) corresponding to the electroluminescence peak at 439 and 444 nm.
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关键词
OLEDs,Blue,Doped device,Chrysene derivatives
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