Stereodefined synthesis of cyclic amidines by domino 1,7-H shift and 6π electrocyclisation

Matthew L. Martin,Claire Wilson,Alistair Boyer

Chemical Communications（2023）

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摘要

Unsaturated -sulfonyl amidines are transformed into valuable N-heterocyclic products when heated with BFOTf. Mechanism studies suggest a domino 1,7-H shift, activating a C-H bond, followed by electrocylisation that results in stereodefined cyclic amidines.

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cyclic amidines,synthesis

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