Bisphenols in water: Occurrence, effects, and mitigation strategies

Bisphenols (bisphenol A (BPA), bisphenol S (BPS), bisphenol F (BPF) and bisphenol AF (BPAF)) are widely used as additives in numerous industries and therefore they are ubiquitously present throughout the world's natural environment including water. A review of the literature is presented on their sources, pathways of entry into the environment, and especially aquatic contexts, their toxicity to humans and other organisms and the technologies for removing them from water. The treatment technologies used are mostly adsorption, biodegradation, advanced oxidation, coagulation, and membrane separation processes. In the adsorption process, several adsorbents, especially carbon-based materials, have been tested. The biodegradation process has been deployed and it involves a variety of micro-organisms. Advanced oxidation processes (AOPs) such as UV/O3-based, catalysis relevant AOPs, electrochemical AOPs and physical AOPs have been employed. Both the biodegradation process and AOPs generate by-products which may be toxic. These by-products need to be subsequently removed using other treatment processes. Effectiveness of the membrane process varies depending on the porosity, charge, hydrophobicity, and other properties of the membrane. The problems and limitations of each treatment technique are discussed and methods to overcome them are presented. Suggestions are articulated to use a combination of processes to improve the removal efficiencies.