"Super stable" Blatter radicals through ArLi addition: surprising chemistry of 7-(trifluoromethyl)benzo[ e ][1,2,4]triazine.

Addition of PhLi to 7-(CF)benzo[][1,2,4]triazine at -78 °C gives the "super stable" Blatter radical in high yields, while above -5 °C two additional products are formed. XRD analysis revealed the formation of a "trimer" and a benzo[][1,2,4]triazepine a novel mechanism. The latter is formed from the anion generated from the isolated radical, which suggests its instability in organic batteries.